具有多个通道的稳健结晶混合固体，表现出高无水质子电导率和宽性能温度范围。
Robust Crystalline Hybrid Solid with Multiple Channels Showing High Anhydrous Proton Conductivity and a Wide Performance Temperature Range.
机构信息
State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.
College of Materials Science and Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.
出版信息
Adv Mater. 2016 Feb 24;28(8):1663-7. doi: 10.1002/adma.201504591. Epub 2015 Dec 10.
A proton conductor displaying high anhydrous proton conductivity (≈10(-2) S cm(-1)) and good performance over a broad temperature range is presented. This hybrid material is produced via doping HCl into open-framework chalcogenide(C2N2H10)(C2N2H9)2 Cu8 Sn3S12, and has cubopolyhedral cavities and multiple channels.
本文提出了一种质子导体，具有高无水质子电导率（≈10(-2) S cm(-1)) 和在较宽温度范围内的良好性能。该混合材料是通过将 HCl 掺杂到具有开放骨架的硫属化物 (C2N2H10)(C2N2H9)2 Cu8 Sn3S12 中制得的，具有多面体形空腔和多个通道。
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