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受污染的生物质飞灰——作为建筑材料再利用的特性及处理优化

Contaminated biomass fly ashes--Characterization and treatment optimization for reuse as building materials.

作者信息

Doudart de la Grée G C H, Florea M V A, Keulen A, Brouwers H J H

机构信息

Department of the Built Environment, Unit Building Physics and Services, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.

Department of the Built Environment, Unit Building Physics and Services, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands; Van Gansewinkel Minerals, Flight Forum 240, Eindhoven, The Netherlands.

出版信息

Waste Manag. 2016 Mar;49:96-109. doi: 10.1016/j.wasman.2015.12.023. Epub 2016 Jan 16.

Abstract

The incineration of treated waste wood generates more contaminated fly ashes than when forestry or agricultural waste is used as fuel. The characteristics of these biomass fly ashes depend on the type of waste wood and incineration process parameters, and their reuse is restricted by their physical, chemical and environmental properties. In this study, four different fly ash types produced by two different incineration plants were analysed and compared to Dutch and European standards on building materials. A combined treatment was designed for lowering the leaching of contaminants and the effect of each treatment step was quantified. A pilot test was performed in order to scale up the treatment. It was found that chlorides (which are the main contaminant in all studied cases) are partly related to the amount of unburnt carbon and can be successfully removed. Other contaminants (such as sulphates and chromium) could be lowered to non-hazardous levels. Other properties (such as particle size, LOI, oxide and mineralogical compositions) are also quantified before and after treatment.

摘要

与将林业或农业废弃物用作燃料相比,经处理的废木材焚烧产生的受污染飞灰更多。这些生物质飞灰的特性取决于废木材的类型和焚烧工艺参数,其再利用受到其物理、化学和环境特性的限制。在本研究中,对两家不同焚烧厂产生的四种不同类型飞灰进行了分析,并与荷兰和欧洲的建筑材料标准进行了比较。设计了一种联合处理方法以降低污染物的浸出,并对每个处理步骤的效果进行了量化。进行了中试试验以扩大处理规模。结果发现,氯化物(在所有研究案例中都是主要污染物)部分与未燃碳的量有关,并且可以成功去除。其他污染物(如硫酸盐和铬)可以降低到无害水平。还对处理前后的其他特性(如粒度、烧失量、氧化物和矿物组成)进行了量化。

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