Rabbani Harris Sajjad, Joekar-Niasar Vahid, Shokri Nima
School of Chemical Engineering and Analytical Science, The University of Manchester, Manchester, United Kingdom.
School of Chemical Engineering and Analytical Science, The University of Manchester, Manchester, United Kingdom.
J Colloid Interface Sci. 2016 Jul 1;473:34-43. doi: 10.1016/j.jcis.2016.03.053. Epub 2016 Mar 25.
Entry capillary pressure is one of the most important factors controlling drainage and remobilization of the capillary-trapped phases as it is the limiting factor against the two-phase displacement. It is known that the entry capillary pressure is rate dependent such that the inertia forces would enhance entry of the non-wetting phase into the pores. More importantly the entry capillary pressure is wettability dependent. However, while the movement of a meniscus into a strongly water-wet pore is well-defined, the invasion of a meniscus into a weak or intermediate water-wet pore especially in the case of angular pores is ambiguous. In this study using OpenFOAM software, high-resolution direct two-phase flow simulations of movement of a meniscus in a single capillary channel are performed. Interface dynamics in angular pores under drainage conditions have been simulated under constant flow rate boundary condition at different wettability conditions. Our results shows that the relation between the half corner angle of pores and contact angle controls the temporal evolution of capillary pressure during the invasion of a pore. By deviating from pure water-wet conditions, a dip in the temporal evolution of capillary pressure can be observed which will be pronounced in irregular angular cross sections. That enhances the pore invasion with a smaller differential pressure. The interplay between the contact angle and pore geometry can have significant implications for enhanced remobilization of ganglia in intermediate contact angles in real porous media morphologies, where pores are very heterogeneous with small shape factors.
入口毛细管压力是控制毛细管捕集相的驱替和再运移的最重要因素之一,因为它是两相驱替的限制因素。众所周知,入口毛细管压力与速率有关,即惯性力会增强非湿相进入孔隙的能力。更重要的是,入口毛细管压力与润湿性有关。然而,虽然弯月面进入强水湿孔隙的运动是明确的,但弯月面侵入弱或中等水湿孔隙,特别是在角形孔隙的情况下,情况却不明确。在本研究中,使用OpenFOAM软件对单个毛细管通道中弯月面的运动进行了高分辨率直接两相流模拟。在不同润湿性条件下的恒定流速边界条件下,模拟了排水条件下角形孔隙中的界面动力学。我们的结果表明,孔隙半角与接触角之间的关系控制着孔隙侵入过程中毛细管压力的时间演化。通过偏离纯水湿条件,可以观察到毛细管压力时间演化中的一个下降,这在不规则角形横截面中会很明显。这使得在较小的压差下孔隙侵入增强。在实际多孔介质形态中,孔隙形状因子很小且非常不均匀,接触角和孔隙几何形状之间的相互作用对于中间接触角下神经节的增强再运移可能具有重要意义。