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基于苯并二氧磷和苯并噻吩衍生物的热激活延迟荧光的高效蓝色有机发光二极管。

High-Efficiency Blue Organic Light-Emitting Diodes Based on Thermally Activated Delayed Fluorescence from Phenoxaphosphine and Phenoxathiin Derivatives.

机构信息

Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.

Center for Organic Photonics and Electronics Research (OPERA), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.

出版信息

Adv Mater. 2016 Jun;28(23):4626-31. doi: 10.1002/adma.201506391. Epub 2016 Apr 5.

DOI:10.1002/adma.201506391
PMID:27059783
Abstract

High-efficiency blue thermally activated delayed fluorescence (TADF) molecules, consisting of phenoxaphosphine oxide and phenoxathiin dioxide as acceptor units and 9,9-dimethylacridan as a donor unit, are reported. Maximum external electroluminescence quantum efficiencies of up to 20.5% are achieved in blue organic light-emitting diodes (OLEDs) by employing these materials as TADF emitters.

摘要

报告了一种高效的蓝色热激活延迟荧光(TADF)分子,它由苯并氧磷氧化物和苯并噻二唑二酮作为受体单元,9,9-二甲基吖啶作为供体单元组成。通过将这些材料用作 TADF 发射器,在蓝色有机发光二极管(OLED)中实现了高达 20.5%的最大外部电致发光量子效率。

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