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模拟厌氧/缺氧反应器处理生活污水过程中的同步碳氮去除(SCNR)

Modeling simultaneous carbon and nitrogen removal (SCNR) in anaerobic/anoxic reactor treating domestic wastewater.

作者信息

Mendes Carlos, Esquerre Karla, Queiroz Luciano Matos

机构信息

Federal University of Bahia, Salvador-Ba, Brazil.

Federal University of Bahia, Salvador-Ba, Brazil.

出版信息

J Environ Manage. 2016 Jul 15;177:119-28. doi: 10.1016/j.jenvman.2016.04.016. Epub 2016 Apr 16.

Abstract

This paper presents a mathematical model based on the Anaerobic Digestion Model No. 1 (ADM1) to simulate the effects of nitrate concentration and hydraulic retention time (HRT) on the simultaneous carbon and nitrogen removal (SCNR) in anaerobic/anoxic reactor treating domestic wastewater. The model was calibrated using previously published experimental data obtained from anaerobic batch tests for different COD/ [Formula: see text] ratios. Model simulations were performed to predict the SCNR in a completely mixed reactor (CSTR) operating under mesophilic conditions (35 °C). Six different scenarios were evaluated to investigate the performance of the SCNR based on typical influent characteristics of domestic wastewater. The variables analyzed were chemical oxygen demand (COD) removal, nitrate concentration, methane production, nitrogen gas, volatile fatty acids (VFA) concentration, pH and percentage of COD used by the denitrifying and methanogenic microorganisms. The HRT was decreased stepwise from 15 to 4 h. The results indicate that Scenario (S5) with a COD/ [Formula: see text] ratio equal to 10 and an HRT equal to 15 h ensures the occurrence of the stable SCNR. Furthermore, the accumulation of denitrification intermediates and a significant reduction in the biogas production when the organic matter is limited was verified.

摘要

本文提出了一种基于1号厌氧消化模型(ADM1)的数学模型,以模拟硝酸盐浓度和水力停留时间(HRT)对处理生活污水的厌氧/缺氧反应器中同时进行碳氮去除(SCNR)的影响。该模型使用先前发表的针对不同COD/[公式:见正文]比率的厌氧批次试验获得的实验数据进行校准。进行模型模拟以预测在中温条件(35°C)下运行的完全混合反应器(CSTR)中的SCNR。评估了六种不同的情况,以根据生活污水的典型进水特征研究SCNR的性能。分析的变量包括化学需氧量(COD)去除、硝酸盐浓度、甲烷产量、氮气、挥发性脂肪酸(VFA)浓度、pH值以及反硝化和产甲烷微生物利用的COD百分比。HRT从15小时逐步降至4小时。结果表明,COD/[公式:见正文]比率等于10且HRT等于15小时的情况(S5)可确保稳定的SCNR发生。此外,还验证了在有机物有限时反硝化中间产物的积累以及沼气产量的显著降低。

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