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用于高效染料敏化太阳能电池的超长锐钛矿 TiO2 纳米线阵列。

Ultralong Rutile TiO2 Nanowire Arrays for Highly Efficient Dye-Sensitized Solar Cells.

机构信息

Key Laboratory for Photonic and Electric Bandgap Materials, Ministry of Education, Harbin Normal University , Harbin 150025, China.

State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences , Changchun 130022, China.

出版信息

ACS Appl Mater Interfaces. 2016 Jun 1;8(21):13384-91. doi: 10.1021/acsami.6b01508. Epub 2016 May 17.

Abstract

Vertically aligned rutile TiO2 nanowire arrays (NWAs) with lengths of ∼44 μm have been successfully synthesized on transparent, conductive fluorine-doped tin oxide (FTO) glass by a facile one-step solvothermal method. The length and wire-to-wire distance of NWAs can be controlled by adjusting the ethanol content in the reaction solution. By employing optimized rutile TiO2 NWAs for dye-sensitized solar cells (DSCs), a remarkable power conversion efficiency (PCE) of 8.9% is achieved. Moreover, in combination with a light-scattering layer, the performance of a rutile TiO2 NWAs based DSC can be further enhanced, reaching an impressive PCE of 9.6%, which is the highest efficiency for rutile TiO2 NWA based DSCs so far.

摘要

通过简便的一步溶剂热法,成功地在透明导电掺氟氧化锡(FTO)玻璃上合成了长度约为 44μm 的垂直排列的锐钛矿 TiO2 纳米线阵列(NWAs)。通过调整反应溶液中的乙醇含量,可以控制 NWAs 的长度和线对线距离。通过采用优化的锐钛矿 TiO2 NWAs 用于染料敏化太阳能电池(DSCs),实现了显著的功率转换效率(PCE)为 8.9%。此外,通过与光散射层结合,锐钛矿 TiO2 NWAs 基 DSC 的性能可以进一步提高,达到令人印象深刻的 PCE 为 9.6%,这是迄今为止基于锐钛矿 TiO2 NWA 的 DSCs 的最高效率。

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