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用于高性能超级电容器的南瓜衍生多孔碳。

Pumpkin-Derived Porous Carbon for Supercapacitors with High Performance.

机构信息

College of Chemical Engineering, Sichuan University, No. 24 South Section 1, Yihuan Road, Chengdu, 610065, P. R. China.

Institute of New Energy and Low-Carbon Technology, Sichuan University, No. 24 South Section 1, Yihuan Road, Chengdu, 610065, P. R. China.

出版信息

Chem Asian J. 2016 Jun 21;11(12):1828-36. doi: 10.1002/asia.201600303. Epub 2016 May 25.

Abstract

Pumpkin has been employed for the first time as a renewable, low-cost precursor for the preparation of porous carbon materials with excellent performance. Unlike most other precursors, pumpkin is rich in sugars and starch, and it has advantageous properties for large-scale production. The as-prepared materials adopted a unique morphology that consisted of numerous fused sphere-like carbon grains with a high specific surface area (2968 m(2)  g(-1) ), abundant micro and mesopores, and excellent electrochemical properties. The pumpkin-derived activated carbon (PAC) material not only exhibited a high specific capacitance of 419 F g(-1) , but also showed considerable cycling stability, with 93.6 % retention after 10 000 cycles. Moreover, a symmetrical supercapacitor that was based on PAC showed a high energy density of 22.1 W h kg(-1) in aqueous electrolyte. These superior properties demonstrate that PAC holds great promise for applications in electrochemical energy-storage devices.

摘要

南瓜首次被用作一种可再生、低成本的前体,用于制备具有优异性能的多孔碳材料。与大多数其他前体不同,南瓜富含糖和淀粉,并且具有大规模生产的优势。所制备的材料采用了独特的形态,由许多融合的球状碳颗粒组成,具有高比表面积(2968 m2 g-1)、丰富的微孔和中孔,以及优异的电化学性能。由南瓜衍生的活性炭(PAC)材料不仅表现出高比电容 419 F g-1,而且还表现出相当好的循环稳定性,在 10000 次循环后保留率为 93.6%。此外,基于 PAC 的对称超级电容器在水电解质中表现出 22.1 W h kg-1的高能量密度。这些优异的性能表明,PAC 在电化学储能器件中的应用具有很大的潜力。

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