College of Chemical Engineering, Sichuan University, No. 24 South Section 1, Yihuan Road, Chengdu, 610065, P. R. China.
Institute of New Energy and Low-Carbon Technology, Sichuan University, No. 24 South Section 1, Yihuan Road, Chengdu, 610065, P. R. China.
Chem Asian J. 2016 Jun 21;11(12):1828-36. doi: 10.1002/asia.201600303. Epub 2016 May 25.
Pumpkin has been employed for the first time as a renewable, low-cost precursor for the preparation of porous carbon materials with excellent performance. Unlike most other precursors, pumpkin is rich in sugars and starch, and it has advantageous properties for large-scale production. The as-prepared materials adopted a unique morphology that consisted of numerous fused sphere-like carbon grains with a high specific surface area (2968 m(2) g(-1) ), abundant micro and mesopores, and excellent electrochemical properties. The pumpkin-derived activated carbon (PAC) material not only exhibited a high specific capacitance of 419 F g(-1) , but also showed considerable cycling stability, with 93.6 % retention after 10 000 cycles. Moreover, a symmetrical supercapacitor that was based on PAC showed a high energy density of 22.1 W h kg(-1) in aqueous electrolyte. These superior properties demonstrate that PAC holds great promise for applications in electrochemical energy-storage devices.
南瓜首次被用作一种可再生、低成本的前体,用于制备具有优异性能的多孔碳材料。与大多数其他前体不同,南瓜富含糖和淀粉,并且具有大规模生产的优势。所制备的材料采用了独特的形态,由许多融合的球状碳颗粒组成,具有高比表面积(2968 m2 g-1)、丰富的微孔和中孔,以及优异的电化学性能。由南瓜衍生的活性炭(PAC)材料不仅表现出高比电容 419 F g-1,而且还表现出相当好的循环稳定性,在 10000 次循环后保留率为 93.6%。此外,基于 PAC 的对称超级电容器在水电解质中表现出 22.1 W h kg-1的高能量密度。这些优异的性能表明,PAC 在电化学储能器件中的应用具有很大的潜力。