一种用于合成单层保护的无定形碳酸钙簇的溶剂热法。
A solvothermal method for synthesizing monolayer protected amorphous calcium carbonate clusters.
作者信息
Sun Shengtong, Gebauer Denis, Cölfen Helmut
机构信息
Department of Chemistry, Physical Chemistry, University of Konstanz, Universitätsstrasse 10, Box 714, D-78457 Konstanz, Germany.
出版信息
Chem Commun (Camb). 2016 May 19;52(43):7036-8. doi: 10.1039/c6cc03010f.
PMID:27161807
Abstract
A solvothermal method was developed for synthesizing organic monolayer protected amorphous calcium carbonate clusters using 10,12-pentacosadiynoic acid as ligand, ethanol as solvent and NaHCO3 decomposition as CO2 source, which can be extended to synthesize other monolayer protected mineral clusters.
摘要
开发了一种溶剂热法，以10,12-二十五碳二炔酸为配体、乙醇为溶剂、碳酸氢钠分解产生的二氧化碳为二氧化碳源，用于合成有机单层保护的无定形碳酸钙簇，该方法可扩展用于合成其他单层保护的矿物簇。
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