Lemos Bruno R S, Soares Érico A R, Teixeira Ana Paula C, Ardisson José D, Fernandez-Outon Luis E, Amorim Camila C, Lago Rochel M, Moura Flávia C C
Departamento de Química, Universidade Federal de Minas Gerais, Belo Horizonte, 31270-901, Brazil.
Laboratório de Física Aplicada, Centro de Desenvolvimento da Tecnologia Nuclear - CDTN/CNEN, MG, 31270-901, Brazil.
Chemosphere. 2016 Sep;159:602-609. doi: 10.1016/j.chemosphere.2016.06.022. Epub 2016 Jun 22.
Amphiphilic magnetic composites were produced based on chrysotile mineral and carbon structures by chemical vapor deposition at different temperatures (600-900 °C) and cobalt as catalyst. The materials were characterized by elemental analysis, X-ray diffraction, vibrating sample magnetometry, adsorption and desorption of N2, Raman spectroscopy, scanning electronic microscopy, and thermal analysis showed an effective growth of carbon structures in all temperatures. It was observed that at 800 and 900 °C, a large amount of carbon structures are formed with fewer defects than at 600 and 700 °C, what contributes to their stability. In addition, the materials present magnetic phases that are important for their application as catalysts and adsorbents. The materials have shown to be very active to remove the oil dispersed in a real sample of emulsified wastewater from biodiesel production and to remove methylene blue by adsorption and oxidation via heterogeneous Fenton mechanism.
基于温石棉矿物和碳结构,通过化学气相沉积法,以钴为催化剂,在不同温度(600 - 900°C)下制备了两亲性磁性复合材料。通过元素分析、X射线衍射、振动样品磁强计、N₂吸附与脱附、拉曼光谱、扫描电子显微镜和热分析对材料进行了表征,结果表明在所有温度下碳结构均有效生长。据观察,在800和900°C时,形成的碳结构数量较多,缺陷比600和700°C时少,这有助于提高其稳定性。此外,这些材料呈现出磁性相,这对其作为催化剂和吸附剂的应用很重要。这些材料已显示出对去除生物柴油生产中乳化废水实际样品中分散的油以及通过非均相芬顿机制吸附和氧化去除亚甲基蓝具有很高的活性。