Kim Dong-Eun, Kang Min-Jae, Park Gwang-Ryeol, Lee Burm-Jong, Kwon Young-Soo, Shin Hoon-Kyu
J Nanosci Nanotechnol. 2016 Jun;16(6):6374-7. doi: 10.1166/jnn.2016.12131.
We synthesized the red emission material, bis(1,4-bis(5-phenyloxazol-2-yl)phenyl) iridium(picolate) [Ir-complexes] and the blue emission material, bis (2-(2-hydroxyphenyl) benzoxazolate)zinc [Zn(HPB)2]. White Organic Light Emitting Diodes were fabricated by using Zn(HPB)2 for a blue emitting layer, Ir-complexes for a red emitting layer and a tris (8-hydroxy quinoline)aluminum [Alq3] for a green emitting layer. The important experimental results obtained, white OLED was fabricated by using double emitting layers of Zn(HPB)2 and Alq3:Ir-complexes, and hole blocking layer of 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline[BCP]. We also varied the thickness of BCP. When the thickness of BCP layer was 5 nm, white emission was achieved. We obtained a maximum luminance of 5400 cd/m2 at a current density of 650 mA/cm2. The CIE coordinates was (0.339, 0.323) at voltage of 10 V.
我们合成了红色发光材料双(1,4 - 双(5 - 苯基恶唑 - 2 - 基)苯基)铱(吡啶甲酸盐)[Ir - 配合物]和蓝色发光材料双(2 - (2 - 羟基苯基)苯并恶唑酸酯)锌[Zn(HPB)₂]。通过使用Zn(HPB)₂作为蓝色发光层、Ir - 配合物作为红色发光层以及三(8 - 羟基喹啉)铝[Alq₃]作为绿色发光层来制备白色有机发光二极管。获得的重要实验结果是,通过使用Zn(HPB)₂和Alq₃:Ir - 配合物的双发光层以及2,9 - 二甲基 - 4,7 - 二苯基 - 1,10 - 菲咯啉[BCP]作为空穴阻挡层制备了白色OLED。我们还改变了BCP的厚度。当BCP层的厚度为5 nm时,实现了白色发光。在电流密度为650 mA/cm²时,我们获得了5400 cd/m²的最大亮度。在10 V电压下,CIE坐标为(0.339, 0.323)。