用于铃木-宫浦偶联反应的硫改性玻璃负载钯纳米颗粒催化剂的开发

Development of a Sulfur-Modified Glass-Supported Pd Nanoparticle Catalyst for Suzuki-Miyaura Coupling.

作者信息

Xiao Mincen, Hoshiya Naoyuki, Fujiki Katsumasa, Honma Tetsuo, Tamenori Yusuke, Shuto Satoshi, Fujioka Hiromichi, Arisawa Mitsuhiro

机构信息

Graduate School of Pharmaceutical Sciences, Osaka University.

出版信息

Chem Pharm Bull (Tokyo). 2016;64(8):1154-60. doi: 10.1248/cpb.c16-00261.

DOI:10.1248/cpb.c16-00261

PMID:27477655

Abstract

A safe, facile and low-leaching (up to 0.17 ppm) sulfur-modified glass-supported palladium nanoparticle catalyst has been developed for the Suzuki-Miyaura coupling of aryl halides with aryl boronic acids. Most notably, this catalyst was highly recyclable and could be used up to 10 times without any discernible decrease in its activity.

摘要

一种安全、简便且低浸出（高达0.17 ppm）的硫改性玻璃负载钯纳米颗粒催化剂已被开发用于芳基卤化物与芳基硼酸的铃木-宫浦偶联反应。最值得注意的是，这种催化剂具有高度可回收性，可重复使用多达10次，而其活性没有任何明显下降。