Song Xiao-yan, Liu Rui, Shui Yong, Kawagishi Tomoki, Zhan Xin-min, Chen Lu-jun
Huan Jing Ke Xue. 2016 May 15;37(5):1873-9.
Stability of short-cut nitrification nitrogen removal performance was studied in a step-feeding, intermittently aerated sequencing batch reactor (IASBR) at 30°C to treat digested piggery wastewater. Results showed that the nitrogen removal was greatly influenced by the ratio of chemical oxygen demand (COD) to total nitrogen (TN) in the influent. Nitrite nitrogen kept accumulating up to 800 mg · L⁻1 when the influent COD/TN ratio was 0.8 ± 0.2, and the removal rates of TN, ammonium nitrogen and total organic carbon (TOC) were only 18.3% ± 12.2%, 84.2% ± 10.3% and 60.7% ± 10.7%, respectively. By contrast, as the influent COD/ TN ratio was increased to 2.4 ± 0.5, the accumulated concentration of nitrite nitrogen sharply decreased from 800 mg · L⁻¹ to below 10 mg-L⁻¹, and the removal rates of TN, ammonium nitrogen and TOC were increased to over 90%, 95% and 85%, respectively. Gradually shortened hydraulic retention time ( HRT) reveales that the ammonia load is a restricting factor for nitrogen removal. The ammonia load should be controlled at no more than 0.30 kg · (m³ · d) ⁻¹, or else, the removal rates of TN, ammonium and TOC would be greatly decreased. The nitrite accumulation rate over the whole run was 74.6%-97.8% and the TN removal rate in the stable phase was over 90%. With efficient and stable short-cut nitrification-denitrification in a low COD/TN, moreover, and unnecessary for addition of alkaline, IASBR shows great advantage for treating wastewater with high concentration of ammonia while low COD/TN ratio.
在30°C下,采用分步进水、间歇曝气序批式反应器(IASBR)处理猪场消化废水,研究了短程硝化脱氮性能的稳定性。结果表明,进水化学需氧量(COD)与总氮(TN)的比值对脱氮效果影响很大。当进水COD/TN比值为0.8±0.2时,亚硝酸盐氮积累至800mg·L⁻¹,此时TN、氨氮和总有机碳(TOC)的去除率分别仅为18.3%±12.2%、84.2%±10.3%和60.7%±10.7%。相比之下,当进水COD/TN比值提高到2.4±0.5时,亚硝酸盐氮的积累浓度从800mg·L⁻¹急剧降至10mg·L⁻¹以下,TN、氨氮和TOC的去除率分别提高到90%以上、95%和85%以上。逐步缩短水力停留时间(HRT)表明,氨负荷是脱氮的限制因素。氨负荷应控制在不超过0.30kg·(m³·d)⁻¹,否则,TN、氨氮和TOC的去除率将大幅下降。整个运行过程中亚硝酸盐积累率为74.6%-97.8%,稳定阶段TN去除率超过90%。此外,在低COD/TN条件下,IASBR能高效稳定地实现短程硝化反硝化,且无需添加碱,在处理高氨氮、低COD/TN比值的废水方面具有很大优势。