Bedemo Agaje, Chandravanshi Bhagwan Singh, Zewge Feleke
Department of Chemistry, College of Natural Sciences, Addis Ababa University, P.O. Box 1176, Addis Ababa, Ethiopia.
Springerplus. 2016 Aug 8;5(1):1288. doi: 10.1186/s40064-016-2983-x. eCollection 2016.
Water is second most essential for human being. Contamination of water makes it unsuitable for human consumption. Chromium ion is released to water bodies from various industries having high toxicity which affects the biota life in these waters. In this study aluminum oxide hydroxide was tested for its efficiency to remove trivalent chromium from aqueous solutions through batch mode experiments. Chromium concentrations in aqueous solutions and tannery waste water before and after adsorption experiments were determined using flame atomic absorption spectrometry. The effects of pH, contact time, initial concentration and adsorbent dosage on the adsorption of Cr(III) were studied. The study revealed that more than 99 % removal of Cr(III) was achieved over wide range of initial pH (3-10). The optimum conditions for the removal of Cr(III) were found to be at pH 4-6 with 40 g/L adsorbent dose at 60 min of contact time. The adsorption capacity was assessed using Langmuir and Freundlich isotherms. The equilibrium data at varying adsorbent dose obeyed the two isotherms. The adsorbent was found to be efficient for the removal of Cr(III) from tannery waste effluent.
水对人类来说是第二重要的必需品。水污染会使其不适于人类饮用。铬离子从各种工业中释放到水体中,其毒性很高,会影响这些水域中的生物群落。在本研究中,通过批次模式实验测试了氢氧化铝去除水溶液中三价铬的效率。使用火焰原子吸收光谱法测定了吸附实验前后水溶液和制革废水中的铬浓度。研究了pH值、接触时间、初始浓度和吸附剂用量对Cr(III)吸附的影响。研究表明,在较宽的初始pH值范围(3-10)内,Cr(III)的去除率超过99%。发现去除Cr(III)的最佳条件是在pH值为4-6、吸附剂剂量为40 g/L、接触时间为60分钟时。使用朗缪尔和弗伦德利希等温线评估吸附容量。不同吸附剂剂量下的平衡数据符合这两种等温线。发现该吸附剂对去除制革废水流出物中的Cr(III)是有效的。