Sun Haitao, Shao Xinru, Ma Zhongsu
College of Food Science and Engineering, Jilin Univ, No. 5333 Xi'an Road, Changchun, 130062, Jilin, PR China.
College of Pharmaceutical and Food Science, Tonghua Normal Univ, No. 950 Yucai Road, Tonghua, 134000, Jilin, PR China.
J Food Sci. 2016 Oct;81(10):E2529-E2537. doi: 10.1111/1750-3841.13427. Epub 2016 Aug 25.
This work aimed to study the effect of nanocrystalline corn straw cellulose (NCSC) and polyethylene glycol (PEG) on the properties of biodegradable corn distarch phosphate (CDP) films. The mechanical properties and barrier properties were investigated. Meanwhile, the compatibility, crystallization, thermal stability, and morphological structure of the films were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (X-RD), thermogravimetric (TGA), and scanning electron microscopy (SEM). In contrast with the CDP films, incorporation of NCSC in the films improved their tensile strength (TS) significantly, and incorporation of PEG improved their elongation at break (EAB) significantly else. PEG, CDP, and NCSC (P-CDP/NCSC) blend films had the best barrier properties. The thermal stability of the films was increased by the incorporation of NCSC. X-RD showed that CDP and NCSC (CDP/NCSC) films had higher crystallinity. SEM revealed that all films had smooth surface, while the films presented a uniform network structure through the incorporation of NCSC.
本研究旨在探讨纳米晶玉米秸秆纤维素(NCSC)和聚乙二醇(PEG)对可生物降解玉米磷酸二淀粉(CDP)薄膜性能的影响。研究了其力学性能和阻隔性能。同时,通过傅里叶变换红外光谱(FT-IR)、X射线衍射(X-RD)、热重分析(TGA)和扫描电子显微镜(SEM)对薄膜的相容性、结晶性、热稳定性和形态结构进行了表征。与CDP薄膜相比,在薄膜中加入NCSC显著提高了其拉伸强度(TS),加入PEG则显著提高了其断裂伸长率(EAB)。PEG、CDP和NCSC(P-CDP/NCSC)共混薄膜具有最佳的阻隔性能。加入NCSC提高了薄膜的热稳定性。X-RD表明CDP和NCSC(CDP/NCSC)薄膜具有更高的结晶度。SEM显示所有薄膜表面光滑,而通过加入NCSC,薄膜呈现出均匀的网络结构。