Department of Environmental Engineering, Technical University of Denmark , DK-2800 Kgs. Lyngby, Denmark.
Institute for Water Quality, Resources and Waste Management, Vienna University of Technology , Karlsplatz 13, 1040 Wien, Austria.
Environ Sci Technol. 2016 Nov 15;50(22):12302-12311. doi: 10.1021/acs.est.6b01791. Epub 2016 Sep 20.
This study provides a systematic approach for assessment of contaminants in materials for recycling. Paper recycling is used as an illustrative example. Three selected chemicals, bisphenol A (BPA), diethylhexyl phthalate (DEHP) and mineral oil hydrocarbons (MOHs), are evaluated within the paper cycle. The approach combines static material flow analysis (MFA) with dynamic material and substance flow modeling. The results indicate that phasing out of chemicals is the most effective measure for reducing chemical contamination. However, this scenario was also associated with a considerable lag phase (between approximately one and three decades) before the presence of chemicals in paper products could be considered insignificant. While improved decontamination may appear to be an effective way of minimizing chemicals in products, this may also result in lower production yields. Optimized waste material source-segregation and collection was the least effective strategy for reducing chemical contamination, if the overall recycling rates should be maintained at the current level (approximately 70% for Europe). The study provides a consistent approach for evaluating contaminant levels in material cycles. The results clearly indicate that mass-based recycling targets are not sufficient to ensure high quality material recycling.
本研究提供了一种系统的方法来评估可回收材料中的污染物。以纸张回收为例进行了说明。在纸张循环中评估了三种选定的化学物质,双酚 A(BPA)、邻苯二甲酸二(2-乙基己基)酯(DEHP)和矿物油碳氢化合物(MOHs)。该方法结合了静态物质流分析(MFA)和动态物质及物质流建模。结果表明,淘汰化学物质是减少化学污染最有效的措施。然而,在纸制品中化学物质的存在可以被认为微不足道之前,这种情况也伴随着相当长的滞后阶段(大约一到三十年)。虽然改进的去污可能是使产品中化学物质最小化的有效方法,但这也可能导致产量降低。如果要将整体回收利用率维持在当前水平(欧洲约为 70%),那么优化的废物源头分类和收集是减少化学污染最无效的策略。本研究为评估物质循环中的污染物水平提供了一种一致的方法。结果清楚地表明,基于质量的回收目标不足以确保高质量的材料回收。