Xu Yunze, Li Kaiqiang, Liu Liang, Yang Lujia, Wang Xiaona, Huang Yi
School of Naval Architecture and Ocean Engineering, Dalian University of Technology, Dalian 116024, China.
School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024, China.
Sensors (Basel). 2016 Sep 8;16(9):1451. doi: 10.3390/s16091451.
In this paper, a new kind of carbon steel (CS) and stainless steel (SS) galvanic sensor system was developed for the study of rebar corrosion in different pore solution conditions. Through the special design of the CS and SS electronic coupons, the electronic resistance (ER) method and zero resistance ammeter (ZRA) technique were used simultaneously for the measurement of both the galvanic current and the corrosion depth. The corrosion processes in different solution conditions were also studied by linear polarization resistance (LPR) and the measurements of polarization curves. The test result shows that the galvanic current noise can provide detailed information of the corrosion processes. When localized corrosion occurs, the corrosion rate measured by the ER method is lower than the real corrosion rate. However, the value measured by the LPR method is higher than the real corrosion rate. The galvanic current and the corrosion current measured by the LPR method shows linear correlation in chloride-containing saturated Ca(OH)₂ solution. The relationship between the corrosion current differences measured by the CS electronic coupons and the galvanic current between the CS and SS electronic coupons can also be used to evaluate the localized corrosion in reinforced concrete.
本文开发了一种新型碳钢(CS)和不锈钢(SS)电偶传感器系统,用于研究不同孔隙溶液条件下钢筋的腐蚀情况。通过对CS和SS电子试件的特殊设计,同时采用电阻(ER)法和零电阻电流表(ZRA)技术来测量电偶电流和腐蚀深度。还通过线性极化电阻(LPR)和极化曲线测量研究了不同溶液条件下的腐蚀过程。测试结果表明,电偶电流噪声可以提供腐蚀过程的详细信息。当发生局部腐蚀时,用ER法测得的腐蚀速率低于实际腐蚀速率。然而,用LPR法测得的值高于实际腐蚀速率。在含氯饱和Ca(OH)₂溶液中,LPR法测得的电偶电流与腐蚀电流呈线性相关。CS电子试件测得的腐蚀电流差值与CS和SS电子试件之间的电偶电流之间的关系,也可用于评估钢筋混凝土中的局部腐蚀。