Nordén Bengt
Chair Professor of Physical Chemistry, Chalmers University of Technology,SE-41296 Gothenburg,Sweden.
Q Rev Biophys. 2016 Jan;49:e17. doi: 10.1017/S0033583516000111. Epub 2016 Aug 31.
Einstein was wrong with his 1927 Solvay Conference claim that quantum mechanics is incomplete and incapable of describing diffraction of single particles. However, the Einstein-Podolsky-Rosen paradox of entangled pairs of particles remains lurking with its 'spooky action at a distance'. In molecules quantum entanglement can be viewed as basis of both chemical bonding and excitonic states. The latter are important in many biophysical contexts and involve coupling between subsystems in which virtual excitations lead to eigenstates of the total Hamiltonian, but not for the separate subsystems. The author questions whether atomic or photonic systems may be probed to prove that particles or photons may stay entangled over large distances and display the immediate communication with each other that so concerned Einstein. A dissociating hydrogen molecule is taken as a model of a zero-spin entangled system whose angular momenta are in principle possible to probe for this purpose. In practice, however, spins randomize as a result of interactions with surrounding fields and matter. Similarly, no experiment seems yet to provide unambiguous evidence of remaining entanglement between single photons at large separations in absence of mutual interaction, or about immediate (superluminal) communication. This forces us to reflect again on what Einstein really had in mind with the paradox, viz. a probabilistic interpretation of a wave function for an ensemble of identically prepared states, rather than as a statement about single particles. Such a prepared state of many particles would lack properties of quantum entanglement that make it so special, including the uncertainty upon which safe quantum communication is assumed to rest. An example is Zewail's experiment showing visible resonance in the dissociation of a coherently vibrating ensemble of NaI molecules apparently violating the uncertainty principle. Einstein was wrong about diffracting single photons where space-like anti-bunching observations have proven recently their non-local character and how observation in one point can remotely affect the outcome in other points. By contrast, long range photon entanglement with immediate, superluminal response is still an elusive, possibly partly misunderstood issue. The author proposes that photons may entangle over large distances only if some interaction exists via fields that cannot propagate faster than the speed of light. An experiment to settle this 'interaction hypothesis' is suggested.
爱因斯坦在1927年索尔维会议上声称量子力学是不完备的,无法描述单个粒子的衍射,这一观点是错误的。然而,粒子纠缠对的爱因斯坦-波多尔斯基-罗森悖论仍然潜藏着其“幽灵般的超距作用”。在分子中,量子纠缠可被视为化学键合和激子态的基础。后者在许多生物物理环境中都很重要,涉及子系统之间的耦合,其中虚拟激发导致总哈密顿量的本征态,但单独的子系统并非如此。作者质疑是否可以探测原子或光子系统,以证明粒子或光子可以在大距离上保持纠缠,并展示出令爱因斯坦如此担忧的它们之间的即时通信。一个解离的氢分子被用作零自旋纠缠系统的模型,其角动量原则上可以为此目的进行探测。然而在实际中,由于与周围场和物质的相互作用,自旋会随机化。同样,似乎还没有实验能提供明确的证据,证明在没有相互作用的情况下,单个光子在大距离上仍保持纠缠,或者证明存在即时(超光速)通信。这迫使我们再次思考爱因斯坦提出这个悖论时真正的想法,即对一组相同制备态的波函数进行概率解释,而不是关于单个粒子的陈述。这样一个由许多粒子组成的制备态将缺乏使量子纠缠如此特殊的性质,包括安全量子通信所假定依赖的不确定性。一个例子是泽韦尔的实验,该实验表明在相干振动的碘化钠分子解离过程中出现了明显违反不确定性原理的可见共振。爱因斯坦关于单个光子衍射的观点是错误的,最近类空反聚束观测已经证明了它们的非局域特性,以及在一个点上的观测如何能远程影响其他点上的结果。相比之下,具有即时超光速响应的长程光子纠缠仍然是一个难以捉摸、可能部分被误解的问题。作者提出,只有当存在通过传播速度不超过光速的场的某种相互作用时,光子才可能在大距离上纠缠。文中建议进行一个实验来验证这个“相互作用假设”。