通过六重钯催化芳基化合成破碎的富勒烯C60H24 。
Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation.
作者信息
Dorel Ruth, de Mendoza Paula, Calleja Pilar, Pascual Sergio, González-Cantalapiedra Esther, Cabello Noemí, Echavarren Antonio M
机构信息
Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain; Departament de Química Orgànica i Analítica Universitat Rovira i Virgili C/ Marcel·lí Domingo s/n 43007 Tarragona Spain.
出版信息
European J Org Chem. 2016 Jul;2016(19):3171-3176. doi: 10.1002/ejoc.201600311. Epub 2016 May 2.
The synthesis of a new -symmetric crushed fullerene CH () has been accomplished in three steps from truxene through sixfold palladium-catalyzed intramolecular arylation of a -trialkylated truxene precursor. Laser irradiation of induces cyclodehydrogenation processes that result in the formation of C, as detected by LDI-MS.
一种新的对称破碎富勒烯CH（）已通过从均三苯经三步合成，即通过钯催化的均三苯前体的六重分子内芳基化反应。对其进行激光照射会引发环脱氢过程，如通过激光解吸电离质谱法（LDI-MS）检测到的，该过程会导致C的形成。
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