Culver Sean P, Brutchey Richard L
Department of Chemistry, University of Southern California, Los Angeles, CA 90089, USA.
Dalton Trans. 2016 Nov 15;45(45):18069-18073. doi: 10.1039/c6dt03382b.
A series of Eu-, Tb-, and Tm-doped CaWO phosphor nanocrystals have been synthesized under benign conditions using the vapor diffusion sol-gel method. The high degree of synthetic flexibility inherent to this approach has enabled the synthesis of a CaWO:(Eu,Tb) dual-sensitized white light emitting nanocrystal phosphor upon commercial UV excitation at 366 nm with a long lifetime exceeding 1 ms.
采用气相扩散溶胶-凝胶法在温和条件下合成了一系列铕、铽和铥掺杂的钨酸钙荧光粉纳米晶体。该方法固有的高度合成灵活性使得在366 nm的商用紫外光激发下合成出具有超过1 ms长寿命的钨酸钙:(铕,铽)双敏化白光发射纳米晶体荧光粉成为可能。