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源自协同磁损耗和介电损耗的钴纳米颗粒修饰碳纳米管的电磁波吸收性能增强

Improved electromagnetic wave absorption of Co nanoparticles decorated carbon nanotubes derived from synergistic magnetic and dielectric losses.

作者信息

Wu Nannan, Lv Hailong, Liu Jiurong, Liu Yuzhen, Wang Shenyu, Liu Wei

机构信息

Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education and School of Materials Science and Engineering, Shandong University, Jinan, Shandong 250061, People's Republic of China.

State Key Laboratory of Crystal Materials, Shandong University, Shandong 250100, China.

出版信息

Phys Chem Chem Phys. 2016 Nov 23;18(46):31542-31550. doi: 10.1039/c6cp06066h.

Abstract

In this study, we report a feasible way to synthesize carbon nanotube nanocomposites deposited with cobalt nanoparticles (20-30 nm) on the surface (Co/CNTs) to serve as an electromagnetic (EM) wave absorption material. EM absorption measurements indicated that epoxy resin composites with 20 wt% Co/CNTs exhibited an effective EM absorption (RL < -10 dB) in the frequency range of 2.5-20 GHz with an absorber thickness of 1.0 to 6.0 mm. A strong absorption peak (RL = -36.5 dB) appeared at 4.1 GHz as the thickness was 4.0 mm, and the absorption bandwidth (RL < -10 dB) was in the frequency range of 3.6-4.6 GHz. The electromagnetic loss research suggested that the superior EM absorption performances including a light weight, strong absorption, broad frequency scope, and thin thickness could be ascribed to the synergistic effect of magnetic loss from Co nanoparticles and the dielectric loss of CNTs, resulting in better impedance matching.

摘要

在本研究中,我们报告了一种可行的方法来合成表面沉积有钴纳米颗粒(20 - 30纳米)的碳纳米管纳米复合材料(Co/CNTs),用作电磁(EM)波吸收材料。电磁吸收测量表明,含有20 wt% Co/CNTs的环氧树脂复合材料在2.5 - 20 GHz频率范围内表现出有效的电磁吸收(RL < -10 dB),吸收体厚度为1.0至6.0毫米。当厚度为4.0毫米时,在4.1 GHz处出现一个强吸收峰(RL = -36.5 dB),吸收带宽(RL < -10 dB)在3.6 - 4.6 GHz频率范围内。电磁损耗研究表明,包括重量轻、吸收强、频率范围宽和厚度薄等优异的电磁吸收性能可归因于钴纳米颗粒的磁损耗与碳纳米管的介电损耗的协同效应,从而实现更好的阻抗匹配。

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