Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.
Soft Matter. 2016 Nov 28;12(47):9549-9560. doi: 10.1039/c6sm01939k.
Using numerical simulations, we study the dynamical evolution of particles interacting via competing long-range repulsion and short-range attraction in two dimensions. The particles are compressed using a time-dependent quasi-one dimensional trough potential that controls the local density, causing the system to undergo a series of structural phase transitions from a low density clump lattice to stripes, voids, and a high density uniform state. The compression proceeds via slow elastic motion that is interrupted with avalanche-like bursts of activity as the system collapses to progressively higher densities via plastic rearrangements. The plastic events vary in magnitude from small rearrangements of particles, including the formation of quadrupole-like defects, to large-scale vorticity and structural phase transitions. In the dense uniform phase, the system compresses through row reduction transitions mediated by a disorder-order process. We characterize the rearrangement events by measuring changes in the potential energy, the fraction of sixfold coordinated particles, the local density, and the velocity distribution. At high confinements, we find power law scaling of the velocity distribution during row reduction transitions. We observe hysteresis under a reversal of the compression when relatively few plastic rearrangements occur. The decompressing system exhibits distinct phase morphologies, and the phase transitions occur at lower compression forces as the system expands compared to when it is compressed.
利用数值模拟,我们研究了在二维空间中通过竞争的长程排斥和短程吸引相互作用的粒子的动力学演化。粒子通过时变的准一维槽势进行压缩,该势控制局部密度,导致系统经历一系列结构相变,从低密度团簇晶格到条纹、空隙和高密度均匀状态。压缩通过缓慢的弹性运动进行,当系统通过塑性重排逐渐达到更高的密度时,会出现类似于雪崩的活动爆发。这些塑性事件的大小从粒子的小重排(包括形成四极缺陷)到大规模涡度和结构相变不等。在高密度均匀相中,系统通过无序-有序过程介导的行减少跃迁进行压缩。我们通过测量势能、六配位粒子的分数、局部密度和速度分布的变化来描述重排事件。在高约束下,我们在行减少跃迁期间发现速度分布的幂律标度。当相对较少的塑性重排发生时,我们在压缩的反转过程中观察到滞后现象。减压系统表现出不同的相形态,与压缩相比,当系统膨胀时,相变发生在较低的压缩力下。