半萜类化合物(-)-F1839-I以及(-)-珊瑚盘菌素B和D的对映体特异性全合成。
Enantiospecific total syntheses of meroterpenoids (-)-F1839-I and (-)-corallidictyals B and D.
作者信息
Dethe Dattatraya H, Dherange Balu D, Ali Saghir, Parsutkar Mahesh M
机构信息
Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur - 208016, India.
出版信息
Org Biomol Chem. 2016 Dec 20;15(1):65-68. doi: 10.1039/c6ob02322c.
PMID:27853800
Abstract
Enantiospecific total syntheses of spiromeroterpenoid natural products (-)-F1839-I and (-)-corallidictyals B and D were achieved using the environmentally benign and highly atom economical Lewis acid catalysed Friedel-Crafts reaction and a highly regio- and stereoselective spirocyclic C-O bond formation reaction.
摘要
利用环境友好且原子经济性高的路易斯酸催化傅克反应以及高度区域和立体选择性的螺环碳-氧键形成反应，实现了螺环萜类天然产物（-）-F1839-I、（-）-珊瑚藻素B和D的对映体特异性全合成。
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