基于三嗪的高度稳定的无质子转移的AADD型自互补四重氢键体系。
Triazine-Based Highly Stable AADD-Type Self-Complementary Quadruple Hydrogen-Bonded Systems Devoid of Prototropy.
作者信息
Kheria Sanjeev, Rayavarapu Suresh, Kotmale Amol S, Gonnade Rajesh G, Sanjayan Gangadhar J
机构信息
Organic Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India.
Central NMR Facility, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India.
出版信息
Chemistry. 2017 Jan 18;23(4):783-787. doi: 10.1002/chem.201605208. Epub 2016 Dec 12.
A new class of 1,3,5-triazine-based quadruple hydrogen-bonded system featuring AADD-type self-complementary arrays has been developed and characterized. This system forms highly stable molecular duplex in non-polar solvent (K >1.9×10 m in CDCl ) without prototropy-related issues, raising its prospects for application in supramolecular polymer science.
一类具有AADD型自互补阵列的新型基于1,3,5-三嗪的四重氢键体系已被开发并表征。该体系在非极性溶剂（CDCl₃中K >1.9×10⁴ m）中形成高度稳定的分子双链体，且不存在质子转移相关问题，这提高了其在超分子聚合物科学中的应用前景。
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