多硫酸盐 [S O ] ：与 [S O ] 阴离子一起，是否已经达到终点？
Polysulfates [S O ] : With the [S O ] Anion, has the End been Reached?
机构信息
Institut für Anorganische und Analytische Chemie, Justus-Liebig-Universität Gießen, Heinrich-Buff-Ring 17, 35392, Giessen, Germany.
Institut für Chemie, Carl von Ossietzky Universität Oldenburg, Carl-von-Ossietzky Straße 9-11, 26129, Oldenburg, Germany.
出版信息
Angew Chem Int Ed Engl. 2016 Dec 23;55(52):16165-16167. doi: 10.1002/anie.201607629. Epub 2016 Nov 22.
The S O ion was obtained both as rubidium and ammonium salt from the reaction of the respective sulfate with SO . It is the largest polysulfate ion known to date and exhibits a chain of six vertex-connected [SO ] tetrahedra. The unique compound was comprehensively characterized and the bonding within the anion was elucidated by theoretical investigations.
S O+离子是通过相应的硫酸盐与 SO3反应得到的铷盐和铵盐。它是迄今为止已知的最大的多硫酸盐离子，具有由六个顶点相连的[SO4]四面体链。该独特的化合物进行了全面的表征，并通过理论研究阐明了阴离子内的键合。
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