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通过层间横向磁阻研究的 - 型BEDT - TTF盐中的各向异性迁移率和载流子动力学。

Anisotropic mobility and carrier dynamics in the -type BEDT-TTF salts as studied by inter-layer transverse magnetoresistance.

作者信息

Sugawara Shigeharu, Tamura Masafumi

机构信息

Department of Physics, Faculty of Science and Technology, Tokyo University of Science, Yamazaki 2641, Noda, Chiba 278-8510, Japan.

出版信息

Sci Technol Adv Mater. 2013 Jul 23;14(4):045004. doi: 10.1088/1468-6996/14/4/045004. eCollection 2013 Aug.

DOI:10.1088/1468-6996/14/4/045004
PMID:27877597
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5090323/
Abstract

A new method to estimate an in-plane conduction anisotropy in a quasi-two-dimensional (q2D) layered conductor by measuring the inter-layer transverse magnetoresistance is proposed. We applied this method to layered organic conductors -(BEDT-TTF)X (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene, CHS; X = IBr, IBr) by applying magnetic field rotating within the basal plane at 4.2 K. We found the anisotropic behaviour of carrier mobility . From this, anomalous distribution of carrier lifetime on the Fermi surface is derived, by the use of Fermi surface data reported for the materials. Calculations of the non-uniform susceptibility ( ) suggest that carrier scattering is enhanced at specific -points related to partial nesting of the Fermi surface. The present method is thus demonstrated to be an efficient experimental tool to elucidate anisotropic carrier dynamics in q2D conductors.

摘要

提出了一种通过测量层间横向磁阻来估算准二维(q2D)层状导体面内传导各向异性的新方法。我们将此方法应用于层状有机导体-(BEDT-TTF)X(BEDT-TTF = 双(乙撑二硫)四硫富瓦烯,CHS;X = IBr,IBr),在4.2 K下施加在基面内旋转的磁场。我们发现了载流子迁移率的各向异性行为。据此,利用所报道材料的费米面数据,推导出费米面上载流子寿命的反常分布。非均匀磁化率( )的计算表明,在与费米面部分嵌套相关的特定 -点处,载流子散射增强。因此,本方法被证明是阐明q2D导体中各向异性载流子动力学的有效实验工具。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/87da1cea2a1c/TSTA11668623F06.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/8ef483455983/TSTA11668623F01.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/5c8cace9d607/TSTA11668623F02.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/d6f27786156a/TSTA11668623F03.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/589b7c32be16/TSTA11668623F04.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/6d7c8c29460a/TSTA11668623F05.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/87da1cea2a1c/TSTA11668623F06.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/8ef483455983/TSTA11668623F01.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/5c8cace9d607/TSTA11668623F02.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/d6f27786156a/TSTA11668623F03.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/589b7c32be16/TSTA11668623F04.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/6d7c8c29460a/TSTA11668623F05.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c5f/5090323/87da1cea2a1c/TSTA11668623F06.jpg

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本文引用的文献

1
High magnetic fields: a tool for studying electronic properties of layered organic metals.
Chem Rev. 2004 Nov;104(11):5737-82. doi: 10.1021/cr0306891.
2
A novel antiferromagnetic organic superconductor kappa-(BETS)(2)FeBr(4) [where BETS = bis(ethylenedithio)tetraselenafulvalene].
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