铜(0)/Selectfluor 体系促进的邻芳基查尔酮的氧化碳-碳键断裂/环化反应：9,10-菲醌衍生物的意外合成。
Copper(0)/Selectfluor System-Promoted Oxidative Carbon-Carbon Bond Cleavage/Annulation of o-Aryl Chalcones: An Unexpected Synthesis of 9,10-Phenanthraquinone Derivatives.
机构信息
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology , Hangzhou 310014, People's Republic of China.
出版信息
J Org Chem. 2017 Jan 6;82(1):109-118. doi: 10.1021/acs.joc.6b02212. Epub 2016 Dec 9.
PMID:27933862
Abstract
A general and efficient protocol for the synthesis of 9,10-phenanthraquinone derivatives has been successfully developed involving a copper(0)/Selectfluor system-promoted oxidative carbon-carbon bond cleavage/annulation of o-aryl chalcones. A variety of substituted 9,10-phenanthraquinones were synthesized in moderate to good yields under mild reaction conditions.
摘要
一种通用且高效的 9,10-菲醌衍生物合成方法已经成功开发，该方法涉及铜(0)/Selectfluor 体系促进的邻芳基查尔酮的氧化碳-碳键断裂/环化反应。在温和的反应条件下，多种取代的 9,10-菲醌以中等至良好的收率合成。
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