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多组分材料或物品的合格评定:由于测量不确定度导致错误判定的风险——变性酒精的案例研究

Conformity assessment of multicomponent materials or objects: Risk of false decisions due to measurement uncertainty - A case study of denatured alcohols.

作者信息

Kuselman Ilya, Pennecchi Francesca, da Silva Ricardo J N B, Brynn Hibbert D

机构信息

Independent Consultant on Metrology, 4/6 Yarehim St., 7176419 Modiin, Israel.

Istituto Nazionale di Ricerca Metrologica (INRIM), Strada delle Cacce 91, 10135 Turin, Italy.

出版信息

Talanta. 2017 Mar 1;164:189-195. doi: 10.1016/j.talanta.2016.11.035. Epub 2016 Nov 18.

Abstract

Risk of a false decision on conformity of a multicomponent material or object due to measurement uncertainty is discussed. Even if conformity assessment for each component of a material sample is successful, the total probability of a false decision (total consumer's risk or producer's risk) concerning the sample as a whole might still be significant. A model of the total probability of such false decisions is formulated based on the law (theorem) of total probability. It is shown that the total risk can be evaluated as a combination of the particular risks of conformity assessment of sample components. For a more complicated task, i.e. for a larger number of components of a sample under control, the total risk is greater. As a case study, the total probability of false conforming (total consumer's risk) is evaluated for customs control of completely denatured alcohols, where conformity assessment is performed by comparison of chemical analytical test results with the regulatory limits.

摘要

讨论了由于测量不确定度而对多组分材料或物体的合格性做出错误判定的风险。即使对材料样品的每个组分的合格评定都是成功的,但就整个样品而言,做出错误判定的总概率(总消费者风险或生产者风险)可能仍然很大。基于全概率定律(定理)建立了此类错误判定总概率的模型。结果表明,总风险可评估为样品组分合格评定的特定风险的组合。对于更复杂的任务,即对于受控样品中更多数量的组分,总风险更大。作为一个案例研究,对完全变性酒精的海关管制中错误合格的总概率(总消费者风险)进行了评估,其中通过将化学分析测试结果与监管限值进行比较来进行合格评定。

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