基于C-H和C-X键合用于亲电底物活化的有机催化新方法。
New approaches to organocatalysis based on C-H and C-X bonding for electrophilic substrate activation.
作者信息
Nagorny Pavel, Sun Zhankui
机构信息
Chemistry Department, University of Michigan, Ann Arbor, MI 48109, USA.
School of Pharmacy, Shanghai Jiao Tong University, No. 800 Dongchuan Rd., Shanghai 200240, P. R. China.
出版信息
Beilstein J Org Chem. 2016 Dec 23;12:2834-2848. doi: 10.3762/bjoc.12.283. eCollection 2016.
Hydrogen bond donor catalysis represents a rapidly growing subfield of organocatalysis. While traditional hydrogen bond donors containing N-H and O-H moieties have been effectively used for electrophile activation, activation based on other types of non-covalent interactions is less common. This mini review highlights recent progress in developing and exploring new organic catalysts for electrophile activation through the formation of C-H hydrogen bonds and C-X halogen bonds.
氢键供体催化是有机催化中一个迅速发展的子领域。虽然含有N-H和O-H部分的传统氢键供体已被有效地用于亲电试剂活化，但基于其他类型非共价相互作用的活化则不太常见。这篇综述强调了通过形成C-H氢键和C-X卤键来开发和探索用于亲电试剂活化的新型有机催化剂的最新进展。
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