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软模板法构建三维大孔聚吡咯支架

Soft-Template Construction of 3D Macroporous Polypyrrole Scaffolds.

机构信息

Center for Advancing Electronics Dresden (cfaed) & Department of Chemistry and Food Chemistry, Technische Universität Dresden, 01062, Dresden, Germany.

School of Chemistry and Chemical Engineering, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University, 800 Dongchuan Road, 200240, Shanghai, P. R. China.

出版信息

Small. 2017 Apr;13(14). doi: 10.1002/smll.201604099. Epub 2017 Feb 1.

Abstract

A bottom-up approach toward 3D hierarchical macroporous polypyrrole aerogels is demonstrated via soft template-directed synthesis and self-assembly of ultrathin polypyrrole nanosheets in solution, which present interconnected macropores, ultrathin walls, and large specific surface areas, thereby exhibiting a high capacity, satisfactory rate capability, and excellent cycling stability for Na-ion storage.

摘要

通过软模板导向合成和溶液中超薄聚吡咯纳米片的自组装,展示了一种自下而上的 3D 分级大孔聚吡咯气凝胶的方法,其具有相互连接的大孔、超薄壁和大比表面积,因此表现出高容量、令人满意的倍率性能和优异的循环稳定性,可用于钠离子存储。

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