Di--butyl-bis-[-(2-meth-oxy-eth-yl)--methyl-dithio-carbamato-κ,']tin(IV): crystal structure and Hirshfeld surface analysis.

The complete mol-ecule of the title compound, [Sn(CH)(CHNOS)], is generated by a crystallographic mirror plane, with the Sn atom and the two inner methyl-ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The di-thio-carbamate ligand coordinates to the metal atom in an asymmetric mode with the resulting CS donor set defining a skew trapezoidal bipyramidal geometry; the -butyl groups are disposed to lie over the longer Sn-S bonds. Supra-molecular chains aligned along the -axis direction and sustained by methyl-ene-C-H⋯S(weakly coordinating) inter-actions feature in the mol-ecular packing. A Hirshfeld surface analysis reveals the dominance of H⋯H contacts in the crystal.