两种不对称 Wittig [2,3]-重排反应的催化方法。
Two Catalytic Methods of an Asymmetric Wittig [2,3]-Rearrangement.
机构信息
Department of Chemistry, Tallinn University of Technology , Akadeemia tee 15, 12618 Tallinn, Estonia.
出版信息
J Org Chem. 2017 Mar 17;82(6):2889-2897. doi: 10.1021/acs.joc.6b02786. Epub 2017 Mar 7.
PMID:28225271
Abstract
Two different approaches for asymmetric catalytic Wittig [2,3]-rearrangement were developed. Allyloxymalonate derivatives were converted into homoallyl alcohols via organocatalytic or Ca-catalyzed pathways in moderate to high enantioselectivities.
摘要
开发了两种不对称催化 Wittig [2,3]-重排的方法。通过有机催化或钙催化途径，将烯丙氧基丙二酸酯衍生物转化为高对映选择性的偕丙醇。
Zotero 插件