Facile Route to Rare Heterobimetallic Aluminum-Copper and Aluminum-Zinc Selenide Clusters.

作者信息

Li Bin, Li Jiancheng, Liu Rui, Zhu Hongping, Roesky Herbert W

机构信息

State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.

Institut für Anorganische Chemie, Georg-August-Universität , Tammannstraβe 4, 37077 Göttingen, Germany.

出版信息

Inorg Chem. 2017 Mar 20;56(6):3136-3139. doi: 10.1021/acs.inorgchem.7b00012. Epub 2017 Mar 7.

DOI:10.1021/acs.inorgchem.7b00012

PMID:28267313

Abstract

Heterobimetallic aluminum-copper and aluminum-zinc clusters were prepared from the reaction of LAl(SeH) [1; L = HC(CMeNAr) and Ar = 2,6-iPrCH] with (MesCu) and ZnEt, respectively. The resulting clusters with the core structures of AlSeCu and AlSeZn exhibit unique metal-organic frameworks. This is a novel pathway for the synthesis of aluminum-copper and aluminum-zinc selenides. The products have been characterized by spectroscopic methods and single-crystal X-ray structural characterization.

摘要