用于可再生化学品生成的电化学：木糖一锅法电化学脱氧制备δ-戊内酯。
Electrochemistry for the Generation of Renewable Chemicals: One-Pot Electrochemical Deoxygenation of Xylose to δ-Valerolactone.
作者信息
James Olusola O, Sauter Waldemer, Schröder Uwe
机构信息
Institute of Environmental and Sustainable Chemistry, Technical University Braunschweig, Hangenring 30, 38106, Braunschweig, Germany.
Chemistry Unit, Kwara State University, Malete, P.M.B., 1530, Ilorin, Nigeria.
出版信息
ChemSusChem. 2017 May 9;10(9):2015-2022. doi: 10.1002/cssc.201700209. Epub 2017 Apr 13.
In this study, the electrochemical conversion of xylose to δ-valerolactone via carbonyl intermediates is demonstrated. The conversion was achieved in aqueous media and at ambient conditions. This study also demonstrates that the feedstock for production of renewable chemicals and biofuels through electrochemistry can be extended to primary carbohydrate molecules. This is the first report on a one-pot electrochemical deoxygenation of xylose to δ-valerolactone.
在本研究中，展示了木糖通过羰基中间体电化学转化为δ-戊内酯的过程。该转化在水性介质和环境条件下实现。本研究还表明，通过电化学生产可再生化学品和生物燃料的原料可以扩展到初级碳水化合物分子。这是关于木糖一锅法电化学脱氧制备δ-戊内酯的首次报道。
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