Gardiner Nicholas J, Hawkesworth Chris J, Robb Laurence J, Whitehouse Martin J, Roberts Nick M W, Kirkland Christopher L, Evans Noreen J
Department of Earth Sciences, University of Oxford, South Parks Road, Oxford, OX1 3AN, UK.
Centre for Exploration Targeting - Curtin Node, Department of Applied Geology, Western Australian School of Mines, Curtin University, Perth, WA, 6102, Australia.
Sci Rep. 2017 Apr 7;7(1):748. doi: 10.1038/s41598-017-00832-2.
Granitoid-hosted mineral deposits are major global sources of a number of economically important metals. The fundamental controls on magma metal fertility are tectonic setting, the nature of source rocks, and magma differentiation. A clearer understanding of these petrogenetic processes has been forged through the accessory mineral zircon, which has considerable potential in metallogenic studies. We present an integrated zircon isotope (U-Pb, Lu-Hf, O) and trace element dataset from the paired Cu-Au (copper) and Sn-W (tin) magmatic belts in Myanmar. Copper arc zircons have juvenile εHf (+7.6 to +11.5) and mantle-like δO (5.2-5.5‰), whereas tin belt zircons have low εHf (-7 to -13) and heavier δO (6.2-7.7‰). Variations in zircon Hf and U/Yb reaffirm that tin belt magmas contain greater crustal contributions than copper arc rocks. Links between whole-rock Rb/Sr and zircon Eu/Eu* highlight that the latter can monitor magma fractionation in these systems. Zircon Ce/Ce* and Eu/Eu* are sensitive to redox and fractionation respectively, and here are used to evaluate zircon sensitivity to the metallogenic affinity of their host rock. Critical contents of Sn in granitic magmas, which may be required for the development of economic tin deposits, are marked by zircon Eu/Eu* values of ca. ≤0.08.
花岗岩型矿床是全球多种具有重要经济价值金属的主要来源。岩浆金属丰度的基本控制因素是构造环境、源岩性质和岩浆分异作用。通过副矿物锆石,人们对这些成岩过程有了更清晰的认识,锆石在成矿研究中具有很大潜力。我们展示了来自缅甸成对的铜金(铜)和锡钨(锡)岩浆带的综合锆石同位素(U-Pb、Lu-Hf、O)和微量元素数据集。铜弧带锆石具有年轻的εHf值(+7.6至+11.5)和类似地幔的δO值(5.2 - 5.5‰),而锡带锆石的εHf值较低(-7至-13)且δO值较重(6.2 - 7.7‰)。锆石Hf和U/Yb的变化再次证实,锡带岩浆比铜弧岩含有更多的地壳成分。全岩Rb/Sr与锆石Eu/Eu之间的联系表明,后者可以监测这些体系中的岩浆分异作用。锆石Ce/Ce和Eu/Eu分别对氧化还原和分异敏感,在此用于评估锆石对其寄主岩石成矿亲和力的敏感性。经济锡矿床形成可能所需的花岗岩岩浆中Sn的临界含量,以锆石Eu/Eu值约≤0.08为标志。