二水合二氯双-[-(5,5-二甲基-4,5-二氢-3-吡咯-2-基-κ)乙酰胺]钯(II)的晶体结构
Crystal structure of -di-chloridobis-[-(5,5-di-methyl-4,5-di-hydro-3-pyrrol-2-yl-κ)acetamide]palladium(II) dihydrate.
作者信息
Lasri Jamal, Eltayeb Naser Eltaher, Haukka Matti, Babgi Bandar A
机构信息
Department of Chemistry, Rabigh College of Science and Arts, PO Box 344, King Abdulaziz University, Jeddah, Saudi Arabia.
University of Jyväskylä, Department of Chemistry, University of Jyväskylä, PO Box 35, FI-40014, Finland.
出版信息
Acta Crystallogr E Crystallogr Commun. 2017 Mar 17;73(Pt 4):528-530. doi: 10.1107/S2056989017003929. eCollection 2017 Apr 1.
The title complex, [PdCl(CHNO)]·2HO, was obtained by N-O bond cleavage of the oxa-diazo-line rings of the -[di-chlorido-bis-(2,5,5-trimethyl-5,6,7,7a-tetra-hydro-pyrrolo-[1,2-][1,2,4]oxa-diazole-)]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by two -arranged chloride anions and a nitro-gen atom from each of the two neutral organic ligands. In the crystal, N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds link complex mol-ecules into double layers parallel to the plane.
标题配合物[PdCl(CHNO)]·2HO是通过[二氯双(2,5,5-三甲基-5,6,7,7a-四氢吡咯并-[1,2-][1,2,4]恶二唑-)]钯(II)配合物的恶二唑啉环的N-O键断裂得到的。钯(II)原子呈现出近乎平面正方形的配位结构，由两个呈 - 排列的氯离子和来自两个中性有机配体中每个配体的一个氮原子提供配位。在晶体中，N-H⋯O、O-H⋯O和O-H⋯Cl氢键将配合物分子连接成平行于 平面的双层结构。
Zotero 插件