Surface-rough Fe-N/C composite wrapped on carbon nanotubes as efficient electrocatalyst for oxygen reduction reaction.

Fe-N/C composites are considered one of the most promising non-precious-metal electrocatalysts for oxygen reduction reaction (ORR). In this paper, we fabricate a novel and efficient carbon nanotube (CNT)-supported Fe-N/C composite catalyst, via the surface-self-polymerization of polydopamine and then the incorporation with Fe species on CNTs, followed by the pyrolysis process. The obtained catalyst demonstrates excellent electrocatalytic performance towards ORR in alkaline media. The modification of Fe-incorporated nitrogen-rich-carbons (Fe-CN) on CNTs lowers the ORR half-wave-potential by ∼190 mV, giving this catalyst with an onset ORR potential of 0.95 V (versus reversible hydrogen electrode (RHE)), a half-wave potential of 0.82 V (versus RHE), and the limiting current density of 5.39 mA cm in 0.1 M KOH. The performance of the as-prepared catalyst is comparatively better than the commercially available Pt/C in terms of positive half-wave potential and larger limiting current, superior durability, and higher tolerance to the methanol.