去质子化的中位羟基卟啉作为一种稳定的π电子阴离子：离子对组装体的构建单元。
Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly.
作者信息
Sasano Yoshifumi, Yasuda Nobuhiro, Maeda Hiromitsu
机构信息
Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu 525-8577, Japan.
出版信息
Dalton Trans. 2017 Jul 18;46(28):8924-8928. doi: 10.1039/c7dt01635b.
PMID:28534579
Abstract
The Ni complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)-porphyrin was synthesized as the precursor of a negatively charged π-electronic system. Deprotonation, which was examined through UV/vis and H NMR spectra, provided an anionic species as the building unit of an ion-pairing assembly in combination with an aliphatic cation.
摘要
5-羟基-10,15,20-三（五氟苯基）卟啉的镍配合物被合成为带负电荷的π电子体系的前体。通过紫外可见光谱和核磁共振氢谱检测的去质子化反应，产生了一种阴离子物种，它与脂肪族阳离子结合，作为离子对组装体的构建单元。
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