Xing Qi, Lv Hui, Xia Chungu, Li Fuwei
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China.
Chem Commun (Camb). 2017 Jun 22;53(51):6914-6917. doi: 10.1039/c7cc03274a.
An efficient palladium-catalyzed oxidative aminocarbonylation of azoles has been developed. This system allows for intermolecular carbonylative cross-coupling of aromatic C(sp)-H bonds with simple amines, which has often been asked for, but has not been realized so far. It provides a straightforward approach to a variety of azol-2-amides.
已开发出一种高效的钯催化唑类氧化氨羰基化反应。该体系实现了芳香族C(sp)-H键与简单胺的分子间羰基化交叉偶联，这一反应一直备受期待，但迄今为止尚未实现。它为多种唑-2-酰胺提供了一种直接的合成方法。
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