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二维沸石在液态聚丁二烯中的剥离

Exfoliation of two-dimensional zeolites in liquid polybutadienes.

作者信息

Sabnis Sanket, Tanna Vijesh A, Li Chao, Zhu Jiaxin, Vattipalli Vivek, Nonnenmann Stephen S, Sheng Guan, Lai Zhiping, Winter H Henning, Fan Wei

机构信息

Chemical Engineering Department, University of Massachusetts, Amherst, Massachusetts 01003, USA.

Polymer Science and Engineering Department, University of Massachusetts, Amherst, Massachusetts 01003, USA.

出版信息

Chem Commun (Camb). 2017 Jul 4;53(52):7011-7014. doi: 10.1039/c7cc03256k. Epub 2017 Jun 16.

Abstract

Layered zeolite precursors were successfully exfoliated by brief shearing or sonication with the assistance of commercially available telechelic liquid polybutadienes at room temperature. The exfoliated zeolite nanosheets can form a stable suspension in an organic solvent, providing exciting potential for the fabrication of zeolite membranes, composite materials and hierarchical zeolites.

摘要

在市售遥爪液体聚丁二烯的辅助下,通过短暂剪切或超声处理,层状沸石前驱体在室温下成功剥离。剥离后的沸石纳米片可在有机溶剂中形成稳定的悬浮液,为沸石膜、复合材料和分级沸石的制备提供了令人兴奋的潜力。

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