气相中的氢氧化钒簇离子：通过SO促进的V-O活化实现双电荷负离子的成键反应
Vanadium Hydroxide Cluster Ions in the Gas Phase: Bond-Forming Reactions of Doubly-Charged Negative Ions by SO -Promoted V-O Activation.
作者信息
Troiani Anna, Rosi Marzio, Garzoli Stefania, Salvitti Chiara, de Petris Giulia
机构信息
Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Roma, Italy.
Dipartimento di Ingegneria Civile e Ambientale, Università di Perugia and ISTM-CNR, Via Duranti 93, 06125, Perugia, Italy.
出版信息
Chemistry. 2017 Sep 4;23(49):11752-11756. doi: 10.1002/chem.201702165. Epub 2017 Jul 5.
The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO has been studied by experimental and computational methods. The obtained results highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the V O skeleton or a terminal V-O bond.
通过实验和计算方法研究了双电荷钒氢氧化物阴离子与SO的气相反应活性。所得结果突出了二氧化硫在促进前所未有的成键反应中的作用，这些反应通过破坏V-O骨架或末端V-O键生成单电荷产物。
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