具有三种不同金属的分子梯形结构的逐步多组分组装。
Stepwise, multicomponent assembly of a molecular trapezoid possessing three different metals.
作者信息
Yao Yuchen, Chakraborty Sourav, Zhu Shiying, Endres Kevin J, Xie Ting-Zheng, Hong Wei, Manandhar Erendra, Moorefield Charles N, Wesdemiotis Chrys, Newkome George R
机构信息
Departments of Polymer Science, University of Akron, Akron, Ohio 44256, USA.
出版信息
Chem Commun (Camb). 2017 Jul 13;53(57):8038-8041. doi: 10.1039/c7cc04080f.
A novel terpyridine-based, trapezoidal architecture was synthesized by a coordination-driven multicomponent assembly and features three different tpy-M-tpy bonds (M = Ru, Fe, and Zn) in the macrocyclic ring. This trimetallic macrocycle introduces the construction of polymetallosupramolecular assemblies possessing multiple, differing metal centers in an ordered, predetermined pattern. Characterization was accomplished by NMR spectroscopy, mass spectrometry, and UV-Vis spectroscopy.
通过配位驱动的多组分组装合成了一种新型的基于三联吡啶的梯形结构，其大环中具有三种不同的tpy-M-tpy键（M = Ru、Fe和Zn）。这种三金属大环引入了具有多个不同金属中心的多金属超分子组装体的构建，这些金属中心以有序、预定的模式排列。通过核磁共振光谱、质谱和紫外-可见光谱进行表征。
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