Universidade Estadual Paulista (UNESP), Instituto de Geociências e Ciências Exatas, Brazil.
Universidade Estadual Paulista (UNESP), Instituto de Geociências e Ciências Exatas, Brazil.
Sci Total Environ. 2017 Dec 31;609:807-814. doi: 10.1016/j.scitotenv.2017.07.194. Epub 2017 Jul 30.
The two-dimensional fractal dimension (D) of large aggregates of kaolin (>540μm) during the shear flocculation process for kaolin solution was investigated using non-intrusive in situ image-based acquisition system. Separate experiments were also carried out for three different sized sub-ranges of large aggregates (0.540-1.125mm; 1.125-1.750mm; 1.750-2.375mm). Digital images were taken at a frequency of 10Hz for 10s for each different pairs of gradients of velocity (G) of 20 and 60s and flocculation times of 2; 3; 4; 5; 10; 20; 30; 60; 120 and 180min. For the same conditions, particle size distribution (PSD) was also determined. Under the investigated conditions, the lowest G produced the greatest D (1.69) at a flocculation time of 30min for the whole range of aggregates. Also, the evolution of the longest length of aggregate (l) and D with time, showed that the dynamic steady-state was reached at different times for each shear rate and l ranges. However, D varied for each size sub-range (ca. 1.1 to 1.8). Finally, the behavior of the aggregate structure may be understood by the predominance of different aggregation mechanisms such as cluster-cluster for G of 60s and particle-cluster for G of 20s.
采用非侵入式原位图像采集系统研究了高岭土溶液剪切絮凝过程中高岭土大团聚体(>540μm)的二维分形维数(D)。还分别进行了三个不同大小的大团聚体亚区间(0.540-1.125mm;1.125-1.750mm;1.750-2.375mm)的三个不同大小的亚区间的实验。对于每个不同的速度梯度(G)对 20 和 60s 和絮凝时间为 2、3、4、5、10、20、30、60、120 和 180min 的情况,以 10Hz 的频率拍摄 10s 的数字图像。对于相同的条件,还确定了颗粒尺寸分布(PSD)。在所研究的条件下,在整个团聚体范围内,最低的 G 在 30min 的絮凝时间下产生最大的 D(1.69)。此外,随着时间的推移,最长的聚合体长度(l)和 D 的演变表明,在不同的剪切速率和 l 范围内,达到了不同的动态稳定状态。然而,每个尺寸亚区间的 D 都有所不同(约为 1.1 到 1.8)。最后,通过不同的团聚机制的优势,如 60s 的簇-簇和 20s 的颗粒-簇,可理解团聚体结构的行为。