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利用时间-温度叠加原理研究热处理木粉对木材/回收高密度聚乙烯复合材料物理力学性能及长期蠕变行为的影响

Effects of Heat-Treated Wood Particles on the Physico-Mechanical Properties and Extended Creep Behavior of Wood/Recycled-HDPE Composites Using the Time-Temperature Superposition Principle.

作者信息

Yang Teng-Chun, Chien Yi-Chi, Wu Tung-Lin, Hung Ke-Chang, Wu Jyh-Horng

机构信息

Department of Forestry, National Chung Hsing University, Taichung 402, Taiwan.

出版信息

Materials (Basel). 2017 Mar 30;10(4):365. doi: 10.3390/ma10040365.

Abstract

This study investigated the effectiveness of heat-treated wood particles for improving the physico-mechanical properties and creep performance of wood/recycled-HDPE composites. The results reveal that the composites with heat-treated wood particles had significantly decreased moisture content, water absorption, and thickness swelling, while no improvements of the flexural properties or the wood screw holding strength were observed, except for the internal bond strength. Additionally, creep tests were conducted at a series of elevated temperatures using the time-temperature superposition principle (TTSP), and the TTSP-predicted creep compliance curves fit well with the experimental data. The creep resistance values of composites with heat-treated wood particles were greater than those having untreated wood particles due to the hydrophobic character of the treated wood particles and improved interfacial compatibility between the wood particles and polymer matrix. At a reference temperature of 20 °C, the improvement of creep resistance () of composites with heat-treated wood particles reached approximately 30% over a 30-year period, and it increased significantly with increasing reference temperature.

摘要

本研究调查了热处理木颗粒对改善木材/再生高密度聚乙烯复合材料物理力学性能和蠕变性能的有效性。结果表明,含有热处理木颗粒的复合材料的含水量、吸水率和厚度膨胀率显著降低,除内结合强度外,未观察到弯曲性能或木螺钉握钉力有所改善。此外,利用时间-温度叠加原理(TTSP)在一系列升高的温度下进行了蠕变试验,TTSP预测的蠕变柔量曲线与实验数据拟合良好。由于处理过的木颗粒具有疏水性且木颗粒与聚合物基体之间的界面相容性得到改善,含有热处理木颗粒的复合材料的抗蠕变值大于含有未处理木颗粒的复合材料。在20℃的参考温度下,含有热处理木颗粒的复合材料在30年期间的抗蠕变性能改善率约为30%,并且随着参考温度的升高而显著增加。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac26/5506928/d5589623bc9a/materials-10-00365-g001.jpg

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