通过孔壁疏水性工程提高金属有机框架上环己烷的选择性氧化
Boosting selective oxidation of cyclohexane over a metal-organic framework by hydrophobicity engineering of pore walls.
作者信息
Li Luyan, Yang Qihao, Chen Si, Hou Xudong, Liu Bo, Lu Junling, Jiang Hai-Long
机构信息
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Suzhou Nano Science and Technology, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
出版信息
Chem Commun (Camb). 2017 Sep 5;53(72):10026-10029. doi: 10.1039/c7cc06166h.
A porphyrinic metal-organic framework (MOF), PCN-222(Fe), was found to exhibit sound activity and selectivity to cyclohexanone and cyclohexanol (known as KA oil) toward cyclohexane oxidation. Remarkably, hydrophobicity engineering of the MOF pore walls led to significantly enhanced activity and selectivity to KA oil, far superior to that of the homogeneous porphyrin catalyst.
一种卟啉金属有机框架（MOF），即PCN - 222(Fe)，被发现对环己烷氧化生成环己酮和环己醇（即所谓的KA油）表现出良好的活性和选择性。值得注意的是，MOF孔壁的疏水工程显著提高了对KA油的活性和选择性，远优于均相卟啉催化剂。
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