Electrostatic Assembly of Platinum Nanoparticles along Electrospun Polymeric Nanofibers for High Performance Electrochemical Sensors.

A novel polyacrylonitrile (PAN) nanofibrous membrane conjugated with platinum nanoparticles (PtNPs) was fabricated by electrospinning and electrostatic assembly techniques. In this procedure, PAN was electrospun with 3-aminopropyltriethoxysilane (APS) together as precursor materials. First, amine groups were introduced onto PAN nanofibers, and then the as-prepared negative-charged platinum nanoparticles (PtNPs) were conjugated onto the surface of the amino-modified PAN nanofibers uniformly by the electrostatic interaction-mediated assembly. The fabricated PAN-PtNPs hybrid nanofibrous membrane was further utilized to modify the glassy carbon electrodes and was used for the fabrication of a non-enzymatic amperometric sensor to detect hydrogen peroxide (H₂O₂). The electrochemical results indicated that, due to the uniform dispersion of PtNPs and the electrostatic interaction between amine groups and PtNPs, the fabricated PAN-PtNPs nanofibrous membrane-based electrochemical sensor showed excellent electrocatalytic activity toward H₂O₂, and the chronoamperometry measurements illustrated that the fabricated sensor had a high sensitivity for detecting H₂O₂. It is anticipated that the strategies used in this work will not only guide the design and fabrication of functional polymeric nanofiber-based biomaterials and nanodevices, but also extend their potential applications in energy storage, cytology, and tissue engineering.