Li Yuhang, Dai Siyi, Zhang Wentao, Zhang Peicong, Qiu Kehui
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, China.
Institute of Materials Science and Technology, Chengdu University of Technology, Chengdu, China.
Luminescence. 2017 Dec;32(8):1593-1596. doi: 10.1002/bio.3387. Epub 2017 Sep 8.
Sr (PO ) :Dy ,Li phosphors were prepared using a simple high temperature solid method for luminescence enhancement. The structures of the as-prepared samples agreed well with the standard phase of Sr (PO ) , even when Dy and Li were introduced. Under ultraviolet excitation at 350 nm, the Sr (PO ) :Dy sample exhibited two emission peaks at 483 nm and 580 nm, which were due to the F → H and F → H transitions of Dy ions, respectively. A white light was fabricated using these two emissions from the Sr (PO ) :Dy phosphors. The luminescence properties of Sr (PO ) :Dy ,Li phosphors, including emission intensity and decay time, were improved remarkably with the addition of Li as the charge compensator, which would promote their application in near-ultraviolet excited white-light-emitting diodes.
采用简单的高温固相法制备了Sr(PO₄)₂:Dy,Li荧光粉以增强发光性能。即使引入了Dy和Li,所制备样品的结构与Sr(PO₄)₂的标准相吻合良好。在350 nm的紫外光激发下,Sr(PO₄)₂:Dy样品在483 nm和580 nm处呈现两个发射峰,分别归因于Dy离子的⁴F₉/₂→⁶H₁₅/₂和⁴F₉/₂→⁶H₁₃/₂跃迁。利用Sr(PO₄)₂:Dy荧光粉的这两种发射光制成了白光。作为电荷补偿剂添加Li后,Sr(PO₄)₂:Dy,Li荧光粉的发光性能,包括发射强度和衰减时间,都得到了显著改善,这将促进它们在近紫外激发白光发光二极管中的应用。