采用高分辨率连续光源石墨炉原子吸收光谱法测定中国茶叶中的铅(Pb)、镉(Cd)、铬(Cr)、铜(Cu)和镍(Ni)。

Determination of Pb (Lead), Cd (Cadmium), Cr (Chromium), Cu (Copper), and Ni (Nickel) in Chinese tea with high-resolution continuum source graphite furnace atomic absorption spectrometry.

作者信息

Zhong Wen-Si, Ren Ting, Zhao Li-Jiao

机构信息

The Experimental High School Attached to Beijing Normal University, Beijing, China.

Beijing Key Laboratory of Environmental and Viral Oncology, College of Life Science and Bioengineering, Beijing University of Technology, Beijing, China.

出版信息

J Food Drug Anal. 2016 Jan;24(1):46-55. doi: 10.1016/j.jfda.2015.04.010. Epub 2015 Jul 18.

Abstract

The contents of lead, cadmium, chromium, copper, and nickel were determined in 25 tea samples from China, including green, yellow, white, oolong, black, Pu'er, and jasmine tea products, using high-resolution continuum source graphite furnace atomic absorption spectrometry. The methods used for sample preparation, digestion, and quantificational analysis were established, generating satisfactory analytical precisions (represented by relative standard deviations ranging from 0.6% to 2.5%) and recoveries (98.91-101.32%). The lead contents in tea leaves were 0.48-10.57 mg/kg, and 80% of these values were below the maximum values stated by the guidelines in China. The contents of cadmium and chromium ranged from 0.01 mg/kg to 0.39 mg/kg and from 0.27 mg/kg to 2.45 mg/kg, respectively, remaining in compliance with the limits stipulated by China's Ministry of Agriculture. The copper contents were 7.73-63.71 mg/kg; only 64% of these values complied with the standards stipulated by the Ministry of Agriculture. The nickel contents ranged from 2.70 mg/kg to 13.41 mg/kg. Consequently, more attention must be paid to the risks of heavy metal contamination in tea. The quantitative method established in this work lays a foundation for preventing heavy metal toxicity in human from drinking tea and will help establish regulations to control the contents of heavy metals in tea.

摘要

采用高分辨率连续光源石墨炉原子吸收光谱法,对来自中国的25个茶叶样品中的铅、镉、铬、铜和镍含量进行了测定。这些茶叶样品包括绿茶、黄茶、白茶、乌龙茶、红茶、普洱茶和茉莉花茶产品。建立了样品制备、消解和定量分析方法,分析精密度令人满意(相对标准偏差为0.6%至2.5%),回收率为98.91 - 101.32%。茶叶中的铅含量为0.48 - 10.57毫克/千克,其中80%的值低于中国相关标准规定的最大值。镉和铬的含量分别为0.01毫克/千克至0.39毫克/千克以及0.27毫克/千克至2.45毫克/千克,均符合中国农业部规定的限量。铜含量为7.73 - 63.71毫克/千克;其中只有64%的值符合农业部规定的标准。镍含量为2.70毫克/千克至13.41毫克/千克。因此,必须更加关注茶叶中重金属污染的风险。本研究建立的定量方法为预防人类因饮茶导致重金属中毒奠定了基础,并将有助于制定控制茶叶中重金属含量的法规。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ab4a/9345429/18ea6bfa7039/jfda-24-01-046f1.jpg

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