Morisue Mitsuhiko, Hoshino Yuki, Shimizu Masaki, Tomita Shogo, Sasaki Sono, Sakurai Shinichi, Hikima Takaaki, Kawamura Ayaka, Kohri Michinari, Matsui Jun, Yamao Takeshi
Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan.
Chem Commun (Camb). 2017 Sep 26;53(77):10703-10706. doi: 10.1039/c7cc06159e.
A metal-lustrous self-standing film, named "porphyrin foil", was formed from a glass-forming polymeric porphyrin. The amorphous glass nature of the porphyrin foil played a key role in spontaneously producing a smooth surface. Its sharp contrast in intense absorption and specular reflection of light at each wavelength provided a brilliant metallic lustre.
一种由玻璃态形成聚合物卟啉制成的具有金属光泽的自立薄膜，被命名为“卟啉箔”。卟啉箔的非晶态玻璃性质在自发产生光滑表面方面起到了关键作用。它在每个波长处对光的强烈吸收和镜面反射形成的鲜明对比赋予了其耀眼的金属光泽。
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