Northwest Normal University, Lanzhou, 730070, China.
Biogeo/Multiphase Chemistry Department, Max Planck Institute for Chemistry, 55128, Mainz, Germany.
Environ Sci Pollut Res Int. 2017 Nov;24(32):25021-25033. doi: 10.1007/s11356-017-0165-1. Epub 2017 Sep 17.
Equivalent black carbon (eBC) mass concentrations were measured by an aethalometer (AE-31) in the Nam Co, central Tibet from 2010 to 2014. Different from previous filter-sampling studies (Ming et al., J Environ Sci 22(11):1748-1756, 2010; Zhao et al., Environ Sci Pollut Res 20:5827-5838, 2013), the first high-resolution online eBC measurement conducted in central Tibet is reported here, allowing to discuss the diurnal variations as well as seasonal variabilities of eBC. Average daily eBC concentration was 74 ± 50 ng/m, reflecting a global background level. Meteorological conditions influenced eBC concentrations largely at seasonal scale, which are higher in February-May but lower in June-January. The highest eBC concentrations (greater than 210 ng/m) were more associated with the W and WSW winds smaller than 6 m/s. The diurnal variations of eBC showed plateaus from 10:00 to 15:00 with seasonal variations, associated with local anthropogenic activities, such as indigenous Tibetan burning animal waste and tourism traffic. The PBLHs showed a co-variance with eBC concentrations, implicating close sources. The aerosol optical depths derived from the MODIS data over the Nam Co Observatory Station (NCOS)-included sub-area (30° N-40° N, 90° E-100° E) showed significant relationship with eBC concentrations. This suggests that nearby or short-distance sources other than long-distance transported pollutants could be important contributors to eBC concentrations at the NCOS, different from the conclusions suggested by previous studies.
2010 年至 2014 年,在西藏纳木错地区,利用黑碳气溶胶吸收光度计(AE-31)测量了等效黑碳(eBC)质量浓度。与以往的滤膜采样研究不同(Ming 等人,J. Environ. Sci. 22(11):1748-1756, 2010; Zhao 等人,Environ. Sci. Pollut. Res. 20:5827-5838, 2013),本文首次报道了在西藏中部进行的高分辨率在线 eBC 测量,这使得我们能够讨论 eBC 的日变化和季节变化。平均日 eBC 浓度为 74±50ng/m,反映了全球背景水平。气象条件在季节尺度上对 eBC 浓度有很大影响,2 月至 5 月较高,6 月至 1 月较低。eBC 浓度最高(大于 210ng/m)与风速小于 6m/s 的西风和西南风更为相关。eBC 的日变化表现出季节性的高原特征,在 10:00 至 15:00 之间保持稳定,与当地人为活动有关,如当地藏族人焚烧动物粪便和旅游交通。边界层高度与 eBC 浓度呈协方差,表明有密切的来源。从 MODIS 数据中得出的纳木错观测站(NCOS)覆盖区域(30°N-40°N,90°E-100°E)的气溶胶光学深度与 eBC 浓度呈显著相关。这表明,与以往研究的结论不同,NCOS 地区的 eBC 浓度可能主要来自附近或短距离源,而不是长距离传输的污染物。