Department of Electrical and Computer Engineering, National University of Singapore , 4 Engineering Drive 3, 117583, Singapore.
Centre for Advanced 2D Materials, National University of Singapore , 6 Science Drive 2, 117546, Singapore.
ACS Appl Mater Interfaces. 2017 Oct 18;9(41):36130-36136. doi: 10.1021/acsami.7b09713. Epub 2017 Oct 9.
The narrow band gap property of black phosphorus (BP) that bridges the energy gap between graphene and transition metal dichalcogenides holds great promise for enabling broadband optical detection from ultraviolet to infrared wavelengths. Despite its rich potential as an intriguing building block for optoelectronic applications, however, very little progress has been made in realizing BP-based infrared photodetectors. Here, we demonstrate a high sensitivity BP phototransistor that operates at a short-wavelength infrared (SWIR) of 2 μm under room temperature. Excellent tunability of responsivity and photoconductive gain are acquired by utilizing the electrostatic gating effect, which controls the dominant photocurrent generation mechanism via adjusting the band alignment in the phototransistor. Under a nanowatt-level illumination, a peak responsivity of 8.5 A/W and a low noise equivalent power (NEP) of less than 1 pW/Hz are achieved at a small operating source-drain bias of -1 V. Our phototransistor demonstrates a simple and effective approach to continuously tune the detection capability of BP photodetectors, paving the way to exploit BP to numerous low-light-level detection applications such as biomolecular sensing, meteorological data collection, and thermal imaging.
黑磷 (BP) 的窄带隙特性使其在能带隙上介于石墨烯和过渡金属二卤化物之间,有望实现从紫外到红外波长的宽带光探测。然而,尽管作为光电应用中引人入胜的构建块具有丰富的潜力,但在实现基于 BP 的红外光电探测器方面几乎没有取得任何进展。在这里,我们展示了一种在室温下工作于短波长红外 (SWIR) 2 μm 的高灵敏度 BP 光电晶体管。通过利用静电栅控效应,实现了响应率和光电导增益的出色可调性,该效应通过调整光电晶体管中的能带排列来控制主导光电流产生机制。在纳瓦级的光照下,在小的工作源-漏偏压-1 V 下,实现了 8.5 A/W 的峰值响应率和低于 1 pW/Hz 的低噪声等效功率 (NEP)。我们的光电晶体管为连续调整 BP 光电探测器的检测能力提供了一种简单而有效的方法,为利用 BP 应用于许多低光水平检测应用铺平了道路,例如生物分子传感、气象数据收集和热成像。